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2D heat and mass transfer modeling of methane steam reforming for hydrogen production in a compact reformer

机译:紧凑型重整炉中甲烷蒸汽重整制氢的二维传热传质建模

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摘要

Compact reformers (CRs) are promising devices for efficient fuel processing. In CRs, a thin solid plate is sandwiched between two catalyst layers to enable efficient heat transfer from combustion duct to the reforming duct for fuel processing. In this study, a 2D heat and mass transfer model is developed to investigate the fundamental transport phenomenon and chemical reaction kinetics in a CR for hydrogen production by methane steam reforming (MSR). Both MSR reaction and water gas shift reaction (WGSR) are considered in the numerical model. Parametric simulations are performed to examine the effects of various structural/operating parameters, such as pore size, permeability, gas velocity, temperature, and rate of heat supply on the reformer performance. It is found that the reaction rates of MSR and WGSR are the highest at the inlet but decrease significantly along the reformer. Increasing the operating temperature raises the reaction rates at the inlet but shows very small influence in the downstream. For comparison, increasing the rate of heat supply raises the reaction rates in the downstream due to increased temperature. A high gas velocity and permeability facilitates gas transport in the porous structure thus enhances reaction rates in the downstream of the reformer.
机译:紧凑型重整器(CR)是用于高效燃料处理的有前途的设备。在CR中,将一块薄实心板夹在两个催化剂层之间,以实现从燃烧管到重整管的高效热传递,以进行燃料处理。在这项研究中,建立了二维传热传质模型,以研究甲烷蒸汽重整(MSR)制氢的CR中的基本迁移现象和化学反应动力学。数值模型中同时考虑了MSR反应和水煤气变换反应(WGSR)。进行参数模拟以检查各种结构/操作参数(例如孔径,渗透率,气体速度,温度和供热速率)对重整器性能的影响。发现MSR和WGSR的反应速率在入口处最高,但沿重整器显着降低。提高工作温度会提高入口处的反应速率,但对下游的影响很小。为了进行比较,由于温度升高,增加供热速率会提高下游的反应速率。较高的气体速度和渗透率有助于气体在多孔结构中的传输,因此提高了重整器下游的反应速率。

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    Ni, M;

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  • 年度 2013
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  • 正文语种 en
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